Activated Carbon
Filters:
Activated carbon (AC) is particles of carbon that have been
treated to increase their surface area and increase their ability to adsorb a
wide range of contaminants - activated carbon is particularly good at adsorbing organic compounds.
You will find two basic kinds of carbon filters Granular
Activated Carbon (GAC) and Solid Block Activated Carbon (SBAC).
Contaminant reduction in AC filters takes place by
two processes, physical removal of contaminant particles,
blocking any that are too large to pass through the pores (obviously,
filters with smaller pores are more effective), and a process called adsorption
by which a variety of dissolved contaminants are
attracted to and held (adsorbed) on the surface of the carbon particles.
The characteristics of the carbon material (particle and pore size,
surface area, surface chemistry, density, and hardness) influence the
efficiency of adsorption.
AC is a highly porous material; therefore, it has an
extremely high surface area for contaminant adsorption. One reference mentions
"The equivalent
surface area of 1 pound of AC ranges from 60 to 150 acres (over 3
football fields)". Another article states, "Under
a scanning electron microscope the activated carbon looks like a porous
bath sponge. This high
concentration of pores within a relatively small volume produces a
material with a phenomenal surface area: one tea spoon of activated
carbon would exhibit a surface area equivalent to that of a football
field." (estimates of surface area vary from different
sources - RJ)
AC is made of tiny clusters of carbon atoms stacked upon one another.
The carbon source is a variety of materials, such as peanut shells,
coconut husks, or
coal. The raw carbon source is slowly heated in the absence of air to
produce a high carbon material. The carbon is activated by passing
oxidizing gases through the material at extremely high temperatures. The
activation process produces the pores that result in such high
adsorptive properties. An article about Activated
Carbon states that "Activated carbon is one of the best
tools which can be used to reduce risks to human health and provide an
aesthetically pleasing product at reasonable cost."
The article also describes how AC works and has some of the best scanning electron microscope
pictures of actual AC granules I have seen. (The
information came from The Via Department of Civil and Environmental
Engineering (CEE) at Virginia Tech and is no longer available)
The adsorption process depends on the following factors: 1) physical
properties of the AC, such as pore size distribution and surface area;
2) the chemical nature of the carbon source, or the amount of oxygen and
hydrogen associated with it; 3) chemical composition and concentration
of the contaminant; 4) the temperature and pH of the water; and 5) the
flow rate or time exposure of water to AC. Interesting
article: What is Activated Carbon,
Adsorption,
History
of AC.
The effectiveness of carbon filters to reduce contaminants
is affected by the factors affecting adsorption
listed above
and three additional characteristics of the
filter, contact time
between the water and the carbon
material, the amount of
carbon in the filter, and pore size.
The length of contact time between the water and the
carbon material, governed by the rate of water
flow and the
amount/volume of activated
carbon, has a significant effect
on adsorption of contaminants. More contact time results in
greater adsorption.
The
amount of carbon present in a cartridge or filter
affects the amount and type of contaminant removed. Less
carbon is required to remove taste- and odor-producing
chemicals than to remove trihalomethanes.
Pore size characteristics will be discussed in greater detail
on
the GAC and SBAC pages, but GAC filters contain loose
granules of
activated carbon while in SBAC filters, the
activated carbon is in the
form of very small particles bound
into a solid, matrix with very small
pores.
Because of the filter characteristics discussed above, the
most
effective Point of Use activated carbon filters are
large SBAC
filtration systems, and the least effective are
the small,
pour-through pitcher filters.
Activated carbon filter cartridges will, over time, become less
effective at reducing contaminants as the pores clog with
particles
(slowing water flow) and the adsorptive surfaces in
the pores become
filled with contaminants (typically not
affecting flow rate). There
is often no noticeable
indication that a carbon filter is no longer
removing
contaminants, so it is important to replace the
cartridge
according to the manufacturer's instructions. The overall
water quality (turbidity or presence of other contaminants)
also affects the capacity of activated carbon to adsorb a
specific contaminant.
It is
important to note, particularly when using counter-top and
faucet-mount carbon filtration systems,
that hot water
should NEVER be run through a carbon filter. I have
seen
warnings about possible damage to the filter from hot
water. Perhaps more
importantly, hot water will tend to
release trapped contaminants into the
water flow potentially
making the water coming out of the filter more
contaminated
than the water going in.
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